溶胶一凝胶法制备二氧化钛及其转化为氮化钛的研究

本文以钛酸丁酯为原料，通过溶胶一凝胶法制备了ＴｉＯ２凝胶，在高温下烧结此凝胶得到ＴｉＯ２。将ＴｉＯ２粉末在９００°Ｃ以上用氨进行氮化，制得金黄色的氮化钛。通过使用热分析、色谱分析、扫描电镜及Ｘ一射线衍射等手段，研究并揭示了凝胶在陶瓷化生成ＴｉＯ２的过程中的化学反应，结晶及晶型随温度的变化规律。发现了氮化钛陶瓷的生成率与ＴｉＯ２溶胶的制备条件之间的关系。     

Burning rate and other characteristics of strontium titanate (SrTiO3) supplemented AP/HTPB/Al composite propellants

In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO₃), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO₃ was characterized for particle size, morphology and material/phase identification (using XRD). By varying SrTiO₃ content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO₃ causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.     

不同含水量超细钛酸钡电流变液性能的研究

采用溶胶-凝胶的方法,通过高温烧结得到了超细钛酸钡(BaTiO3)粉体,烧结产物经SEM、XRD等表征手段对粉体的形貌和晶型进行分析。采用卡尔-费休法测定了配制的电流变液中的含水量,讨论了不同含水量对钛酸钡的电流变性能的影响。结果表明,含水钛酸钡ER液在含水量为117．2μg／g时,屈服应力、表观粘度和漏电流密度达到最大值;要使含水钛酸钡ER液具有一定的ER效应,且在其实验仪器测试范围内(电场强度最大可达2．5kV／mm;漏电流最大可达10μA)具有电流变效应,含水量应小于或等于88．1μg／g。     

钛酸酯偶联剂在铜-环氧屏蔽导电涂料中的用量研究

应用化学键理论,在前人提出的理论模型基础上,考察了一种复合单烷氧型钛酸酯偶联剂在铜-环氧屏蔽导电涂料中的最佳用量问题,结果表明理论值和试验值有很大差别,并对此进行了分析。